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Buy Diazepam Online Valium, a brand name for the drug diazepam, is a widely recognized medication primarily used to treat anxiety disorders, muscle spasms, and alcohol withdrawal symptoms. Available in tablet form, Valium belongs to the benzodiazepine class of drugs, working by enhancing the effects of a neurotransmitter called gamma-aminobutyric acid (GABA) in the brain, resulting in a calming effect on the central nervous system.